Recently I am researching about TRIRUTHENIUM CARBONYL CLUSTER; DIRECTED C-H; HYDROGEN-TRANSFER; 1-AZAVINYLIDENE LIGAND; LESS DEHYDROGENATION; OXIDATIVE ADDITION; COORDINATION MODES; ALKYNE INSERTION; BOND ACTIVATION; ELECTRON-RICH, Saw an article supported by the MCI [CTQ2017-82935-P, PID2019-108429RB-I00, RED2018-102387-T]; Gobierno de AragonGobierno de Aragon [E06_17R]; Fundacion Ramon Areces (XVIII Concurso Nacional de Ayudas a la Investigacion en Ciencias de la Vida y de la Materia) [CIVP18A3938]; Fondo Europeo de Desarrollo Regional (FEDER)European Commission; European Social Fund (FSE)European Social Fund (ESF); MINECO (Spain); Juan de la Cierva-Incorporacion Fellowship. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Buil, ML; Collado, A; Esteruelas, MA; Gomez-Gallego, M; Izquierdo, S; Nicasio, AI; Onate, E; Sierra, MA. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone. Product Details of 119-61-9
Rhodium and iridium diolefin catalysts for the acceptorless and base-free dehydrogenation of secondary alcohols have been prepared, and their degradation has been investigated, during the study of the reactivity of the dimers [M(mu-Cl)(eta(4)-C8H12)] (2) (M = Rh (1), Ir (2)) and [M(mu-OH)(eta(4)-C8H12)](2) (M = Rh (3), Ir (4)) with 1,3-bis(6′-methyl-2′-pyridylimino)isoindoline (HBMePHI). Complex 1 reacts with HBMePHI, in dichloromethane, to afford equilibrium mixtures of 1, the mononuclear derivative RhCl(eta(4)-C8H12){kappa(1)-N-py-(HBMePHI)} (5), and the binuclear species [RhCl(eta(4)-C8H12)](2){mu-N-py,N-py-(HBMePHI)} (6). Under the same conditions, complex 2 affords the iridium counterparts IrCl(eta(4)-C8H12){kappa(1)-N-py-(HBMePHI)} (7) and [IrCl(eta(4)-C8H12)](2){mu-N-py,N-py-(HBMePHI)} (8). In contrast to chloride, one of the hydroxide groups of 3 and 4 promotes the deprotonation of HBMePHI to give [M(eta(4)-C8H12)](2)(mu-OH){mu-N-py,Niso(BMePHI)} (M = Rh (9), Ir (10)), which are efficient precatalysts for the acceptorless and base-free dehydrogenation of secondary alcohols. In the presence of KOtBu, the [BMePHI](-) ligand undergoes three different degradations: alcoholysis of an exocyclic isoindoline-N double bond, alcoholysis of a pyridyl-N bond, and opening of the five-membered ring of the isoindoline core.
Product Details of 119-61-9. Welcome to talk about 119-61-9, If you have any questions, you can contact Buil, ML; Collado, A; Esteruelas, MA; Gomez-Gallego, M; Izquierdo, S; Nicasio, AI; Onate, E; Sierra, MA or send Email.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem