Brief introduction of 616-14-8

The article 《Metal-free C(sp3)-H functionalization of sulfonamides via strain-release rearrangement》 also mentions many details about this compound(616-14-8)Category: thiomorpholine, you can pay attention to it or contacet with the author([email protected]; [email protected]; [email protected]; [email protected]; [email protected]) to get more information.

Category: thiomorpholine. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: 1-Iodo-2-methylbutane, is researched, Molecular C5H11I, CAS is 616-14-8, about Metal-free C(sp3)-H functionalization of sulfonamides via strain-release rearrangement. Author is Hu, Jiefeng; Yang, Xianyu; Shi, Shasha; Cheng, Bo; Luo, Xiaoling; Lan, Yu; Loh, Teck-Peng.

A metal-free reaction system that enables C-H bond functionalization of aliphatic sulfonamides R(CH2)2N(F)Ts (R = decyl, cyclohexyl, oxan-4-yl, benzyl, etc.) using DABCO as a promoter under mild conditions, affording a series of α,β-unsaturated imines R1CH=C(R)CH=NTs (R1 = Ph, 4-chlorophenyl, 2,3-dihydro-1-benzofuran-5-yl, etc.) in good yields with high selectivities was presented. This protocol tolerates a broad range of functionalities and can serve as a powerful synthetic tool for the late-stage modification of complex compounds More importantly, control experiments and detailed DFT calculations suggest that this process involves [2 + 2] cyclization/ring-cleavage reorganization, which opens up a new platform for the establishment of other related reorganization reactions.

The article 《Metal-free C(sp3)-H functionalization of sulfonamides via strain-release rearrangement》 also mentions many details about this compound(616-14-8)Category: thiomorpholine, you can pay attention to it or contacet with the author([email protected]; [email protected]; [email protected]; [email protected]; [email protected]) to get more information.

Reference:
Thiomorpholine – Wikipedia,
Thiomorpholine | C4H9NS – PubChem