Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 616-14-8, is researched, SMILESS is CCC(CI)C, Molecular C5H11IJournal, Angewandte Chemie, International Edition in English called Preparation of (S)-2-methylbutyl and (S)-sec-butyl ketones from optically active 2-methyl-1-butanol by the dithiane method, Author is Seebach, D.; Steinmueller, D., the main research direction is ketone; aldehyde; dithianes.HPLC of Formula: 616-14-8.
Optically active aldehydes and ketones EtMeCHCRO (where R = H, Me, Ph, Me3Si, C5H11, or 1-cyclohexenyl) were prepared by treating EtMeCHCHO, obtained from EtMeCHCH2OH, with CH2(CH2SH)2 to give 2-(1-methylpropyl)-1,3-dithiane, which was then alkylated and hydrolyzed. The loss of optical activity was <20% for the reaction sequence. 《Preparation of (S)-2-methylbutyl and (S)-sec-butyl ketones from optically active 2-methyl-1-butanol by the dithiane method》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(1-Iodo-2-methylbutane)HPLC of Formula: 616-14-8.
Reference:
Thiomorpholine – Wikipedia,
Thiomorpholine | C4H9NS – PubChem