As a society publisher, everything we do is to support the scientific community – so you can trust us to always act in your best interests, and get your work the international recognition that it deserves., Name: 2-Methoxybenzaldehyde, 135-02-4, Name is 2-Methoxybenzaldehyde, molecular formula is C8H8O2, belongs to thiomorpholine compound. In a document, author is Bell, NA, introduce the new discover.
Reactions involving the donors N-methyl-2-methylbenzothiazolium-andN-(1-propyl)-2-methylbenzothiazolium iodide with the acceptor 2,3,5,6-tetramethyl-7,7,8,8-tetracyano-p-quinodimethane (TMTCNQ) in the presence of a suitable base lead to the isolation of novel [(Z)-beta-(N-alkylbenzothiazol-3-ium-2-yl)-alpha-cyano-2,3,5,6-tetramethyl-4-styryl]dicyanomethanide chromophores. Under prolonged reaction periods, these first examples of charge transfer compounds incorporating the distorted TMTCNQ electron acceptor, undergo further reaction at the acrylonitrile functionality promoting the synthesis of novel thiomorpholine-based charge transfer compounds via a sulfur mediated cyclisation reaction. This second reaction illustrates a fundamentally new type of TCNQ-based chemistry as confirmed by X-ray crystallography and high-resolution mass spectrometry. A possible reaction mechanism for the formation of the thiomorpholine-based chromophores is considered.
The result showed that such a combination of chemo- and biocatalysis improved the catalytic yield more than two times compared with that of sole metal catalysis.you can check my other blog about 135-02-4, you can contact me at any time and look forward to more communication. Name: 2-Methoxybenzaldehyde.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem