Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics, Recommanded Product: 607-81-8, 607-81-8, Name is Diethyl benzylmalonate, SMILES is C1=C(CC(C(OCC)=O)C(OCC)=O)C=CC=C1, belongs to thiomorpholine compound. In a document, author is Beller, M, introduce the new discover.
New cationic rhodium-amine complexes and their implication in the catalytic anti-Markovnikov oxidative amination of styrenes
The oxidative anti-Markovnikov amination of styrenes catalyzed by cationic rhodium complexes provides a new access to enamines. As catalyst precursors [Rh(cod)(amine)(2)](+) complexes have been identified and characterized for the first time by X-ray crystallography and NMR. While piperazine, N-methylpiperazine, and thiomorpholine form 1:1 Rh-amine complexes, nonchelating amines such as piperidine and diethylamine form 1:2 Rh-amine complexes. The easier dissociation of the amine ligand explains why monodentate amines give good yields of the corresponding enamines in contrast to bidentate amines. (C) 1998 Elsevier Science S.A. All rights reserved.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 607-81-8. Recommanded Product: 607-81-8.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem